Author's: M. EL-SAADAWY
Pages: [135] - [151]
Received Date: February 25, 2012
Submitted by:
Series of polycrystalline samples of were prepared by usual ceramic methods,
where x = 0.0, 0.4, 0.6, 0.8, 1.0, 1.2, 1.4, and 1.6. X-ray
analysis were obtained at room temperature by using
with confirms the presence of W-type
hexaferrite phase structure. The dc electrical conductivity
and the dielectric constant
were studied. The experimental results
showed that dc resistivity, dielectric constant, Curie temperature,
and activation energies for electrical conduction increase as Cu ion
substitution increases. The dc electrical conductivity increases as
temperature increases. The oxygen diffusion in the samples at
annealing temperature of
for 1 min, was studied. The diffusion
coefficient was calculated by using the equation
It was found that the oxygen diffusion is
characterized by a relatively small activation energy (0.215eV) and
low pre-exponential factors
The substitution of Cu ions decreases the
diffusion coefficient up to x = 1.2 and then increase it.
X-ray analysis, electrical properties, charge carrier concentration,
diffusion coefficient, hexagonal ferrite.