Volume no :8, Issue no: 1, July 2013

MONITORING OF ELECTROCHEMICAL CHLORIDE EXTRACTION (ECE) FROM REINFORCED CONCRETE ELEMENTS

Author's: PAULO S. D. BRITO
Pages: [1] - [26]
Received Date: June 3, 2013
Submitted by:

Abstract

The main objective of this study is to monitor the evolution of ionic conductivity within the recovering layer of reinforced concrete structures by electrochemical chloride extraction (ECE) during treatment operations. The ECE process consists in the application of a direct electrical field between the reinforcement grid, inside the concrete, and an external metallic mesh to promote the migration of chloride anions away from the concrete. Since chloride anions are the main single ions responsible for the reinforced concrete structure corrosion and degradation, ECE is an obvious advantage in terms of concrete structure renovations that are subjected to maritime conditions and in the early stages of concrete contamination, this is a degradation process that is common in coastal areas.

Laboratory tests were made using concrete prisms contaminated with chloride ions in contact with a saturated calcium hydroxide solution. The extraction process was followed by measuring the ionic conductivity using the two pins technique. Two stainless steel rods embedded in the concrete prism were used as pins.
Variations of ionic conductivity with the depth in concrete covering layer are discussed and it is shown that this procedure can be used as a monitoring technique based on the ECE process.

Keywords

electrochemical chloride extraction (ECE), process monitoring, concrete conductivity, concrete corrosion.