Volume no :5, Issue no: 2, April (2012)

MICROSTRUCTURE AND ELECTRODE CHARACTERISTICS OF METAL HYDRIDE ELECTRODE ALLOY

Author's: YU QING QIAO, MIN SHOU ZHAO and LI MIN WANG
Pages: [97] - [106]
Received Date: February 23, 2012
Submitted by:

Abstract

Microstructure and electrode characteristics of metal hydride electrode alloy have been investigated by XRD, FESEM-EDS, and EIS measurements. The result shows that the alloy is mainly composed of V-based solid solution phase with body-centered-cubic structure and TiNi-based secondary phase. The discharge capacity increases with increasing temperature in a wider temperature region from 303K to 343K. The result of electrochemical impedance spectrometry indicates that the charge transfer resistance decreases with increasing temperature, while the exchange current density in the bulk of the alloy increases with increasing temperature.

Keywords

metal hydride electrode, Ni-MH batter, V-based solid solution.