Volume no :19, Issue no: 1, February (2019)

NO GAS DOPING OF ZnO FILMS USING Ir HOT-WIRE IN CATALYTIC REACTION-ASSISTED CHEMICAL VAPOR DEPOSITION

Author's: Ryuta Iba, Yuki Adachi, Ariyuki Kato, Koichiro Oishi, Hironori Katagiri and Kanji Yasui
Pages: [29] - [41]
Received Date: March 26, 2019
Submitted by:
DOI: http://dx.doi.org/10.18642/jmseat_7100122042

Abstract

Nitrogen doping of ZnO films by the decomposition of NO gas using a heated Ir wire during film growth was attempted through the reaction between dimethylzinc (DMZn) and high-temperature High-temperature was produced by the Pt-catalyzed reaction between and Although p-type ZnO films were not obtained, the residual carrier concentration decreased upon the addition of NO gas. In X-ray photoelectron spectra, multiple overlapping N-1s peaks were observed from 395eV to 408eV. By deconvoluting the spectra, components such as Zn-N, N-H, N-N, and were identified. The relative intensity of the Zn-N peak at 395.5eV-396.8eV increased when a heated Ir wire was used to decompose the NO gas.

Keywords

ZnO, catalytic reaction, Ir hot-wire, nitrogen doping.