Volume no :10, Issue no: 1, July (2014)

RAMAN SCATTERING AND OPTICAL ABSORPTION STUDY OF RADIATION EFFECTS IN ALKALI ZINC BOROSILICATE GLASS

Author's: V. V. Lopushansky
Pages: [25] - [38]
Received Date: December 30, 2013
Submitted by:

Abstract

Raman scattering and optical absorption studies of alkali zinc borosilicate glass irradiated with X-rays (up to 1100 Gy) or 7-MeV electrons are reported. We did not observe any Raman evidence for the radiation-induced changes in the glass structure, which could be related to the increasing number of three-member silicate rings and decreasing the average Si–O–Si bond angle. Optical absorption spectra show the formation of three types of colour centres in alkali zinc borosilicate glass similar to other amorphous materials. The observed radiation colour centres partly anneal at post-irradiation storage at room temperature and completely disappear at annealing to 550K.

Keywords

borosilicate glass, irradiation, optical absorption, Raman scattering, colour centres.